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The Rosenmund Reduction is a chemical reaction where an acyl chloride is selectively reduced into an aldehyde. This is achieved through hydrogenation using gaseous hydrogen in the presence of a specific catalyst, typically palladium supported on barium sulphate. The general equation is: R-COCl + H₂ → R-CHO + HCl. Understand the Rosenmund Reduction Mechanism, its steps, and its applications. Also, get answers to frequently asked questions about this important chemical reaction . A hydrogenation process that selectively reduces acyl chlorides to aldehydes with palladium catalyst. Learn about the reaction history, mechanism, catalyst preparation, and related methods. Rosenmund reduction is the hydrogenation of an acyl chloride to an aldehyde, in presence of catalyst (Pd supported on barium sulphate). Barium sulphate partially poisons Pd metal and prevents over-reduction.